Here's some data for you:
I wrote a program in Visual Basic to simulate this game. It plays the game 1,000,000 times, keeping track of the number of times each player wins. It then tabulates the following data:
1) The percentage of wins for the the player who won most often after playing 500,000 games and after 1,000,000 games
2) The percentage of wins for the 2nd most winning player after 500,000 games and after 1,000,000 games
3) The percentage of wins for player #6 after 500,000 games and after 1,000,000 games
4) The percentage of wins for the player who won the least number of games (not player 1) after 500,000 games and after 1,000,000 games
On my computer, the program takes approximately 27 seconds to complete.
Here are my results (in each of the 4 categories, the data for the first 500,000 games is listed first, followed by the data for the entire 1,000,000 games played):
1st program run:
Most wins: Player 2 after 500,000 games (9.6034%), Player 2 after 1,000,000 games (9.6666%)
2nd most wins: Player 5 (9.3842%), Player 11 (9.5847%)
Player 6: 9.3038%, 8.7337%
Least wins: Player 10 (8.5560%), Player 10 (8.5995%)
2nd run:
Most wins: Player 12 (9.8740%), Player 12 (9.4708%)
2nd most wins: Player 11 (9.4456%), Player 5 (9.3190%)
Player 6: 9.3676%, 9.2796%
Least wins: Player 4 (8.5390%), Player 9 (8.6502%)
3rd run:
Most wins: Player 5 (9.5348%), Player 11 (9.5035%)
2nd most wins: Player 3 (9.3450%), Player 12 (9.3111%)
Player 6: 9.2758%, 9.0039%
Least wins: Player 8 (8.3498%), Player 8 (8.7958%)
4th run:
Most wins: Player 12 (9.9604%), Player 7 (9.5820%)
2nd most wins: Player 9 (9.4144%), Player 3 (9.5198%)
Player 6: 9.3296%, 8.9394%
Least wins: Player 10 (8.4282%), Player 5 (8.5131%)
In one run, after 100,000 games, player 5 was the least winning player, but after 1,000,000 games, he was the most winning player.