Reduce the volume of a gas.How much heat, how much pressure?

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SUMMARY

When halving the volume of an ideal gas adiabatically, the pressure increases according to the adiabatic condition, represented by the equation PVγ = K, where γ is the ratio of specific heats (Cp/Cv). The temperature rises because work is done on the gas, increasing its internal energy as the walls of the container compress the gas molecules. Upon rapid compression, the pressure initially climbs and may drop slightly as the gas cools to ambient temperature, consistent with the ideal gas law PV=nRT.

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  • Understanding of the ideal gas law (PV=nRT)
  • Knowledge of adiabatic processes and the adiabatic condition (PVγ = K)
  • Familiarity with the concepts of specific heats (Cp and Cv)
  • Basic principles of thermodynamics, particularly the first law of thermodynamics
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  • Study the derivation and applications of the adiabatic condition in thermodynamics
  • Explore the relationship between internal energy and temperature in gases
  • Investigate real-world applications of adiabatic compression in engineering
  • Learn about the effects of rapid compression and cooling on gas behavior
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peanutaxis
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If I, say, half the volume of a[n ideal] gas adiabatically, how on Earth can I tell how much the pressure will increase and how much the temperature will increase? PV=nRT

Also, by what mechanism does the temperature increase? What would convince the molecules to move any faster? I can see why the pressure would increase due to a larger number of collisions per unit area per unit time, but why would the average speed of a molecule increase?

Last question. If I compress a gas very quickly and it gets hot, and then let it cool off to ambient, will the pressure climb rapidly as I compress it and then drop a little as it cools due to PV=nRT?thanks!
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peanutaxis said:
If I, say, half the volume of a[n ideal] gas adiabatically, how on Earth can I tell how much the pressure will increase and how much the temperature will increase? PV=nRT
If it is compressed adiabatically, one has to use the adiabatic condition: ##PV^\gamma = K##, K being a constant and ##\gamma = \frac{C_p}{C_v}##, i.e. the ratio of specific heats at constant pressure and constant volume. This assumes a reversible compression. In the real world adiabatic compressions are very close to reversible if T and P are fairly uniform throughout the volume of gas during the compression process.

Also, by what mechanism does the temperature increase? What would convince the molecules to move any faster? I can see why the pressure would increase due to a larger number of collisions per unit area per unit time, but why would the average speed of a molecule increase?
Since you are doing work on the gas with no heat flow into or out of the gas, the first law tells you that internal energy has to increase. As the walls move in, the moving walls add energy to the molecules that collide with it.

Last question. If I compress a gas very quickly and it gets hot, and then let it cool off to ambient, will the pressure climb rapidly as I compress it and then drop a little as it cools due to PV=nRT?
Yes.

AM
 

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