Relationship between work, internal energy and enthelpy.

AI Thread Summary
Work produced by a steam turbine can be related to both internal energy (ΔU) and enthalpy (ΔH), depending on the specific process conditions. In general, for a quasi-static, constant-pressure process, the relationship ΔH=ΔQ is applicable, while for an adiabatic process, ΔU=-ΔW is used. The discussion emphasizes that enthalpy accounts for internal energy and flow work, making it relevant for calculating work in turbine operations. Ultimately, the context of the thermodynamic process determines whether to use ΔU or ΔH for work calculations. Understanding these relationships is crucial for analyzing energy transfers in thermodynamic systems.
zzinfinity
Messages
47
Reaction score
0
Hi,
I'm taking a thermodynamics class and I'm stuck on how work relates to enthalpy and internal energy.
Does work done by a system equal change in internal energy, change in enthalpy or does it depend on the situation?

The question I'm stuck on asks for the work produced by a steam turbine and gives initial and final properties for the steam. I feel like the work produced by the turbine is just equal to the ΔU for the steam, but I could also see an argument for using ΔH. Any thoughts would be appreciated.
 
Science news on Phys.org
Mass flowing across a control surface brings energy (neglecting potential and kinetic energy changes):

u + P \nu

where,

u = fluid specific internal energy
P = fluid static pressure
\nu = fluid specific volume

But this is the definition of enthalpy:

h = u + P \nu

So enthalpy includes the internal energy and the "flow work" term P \nu.

So for your turbine you will use Δh as you mentioned.
 
The work done by a system depends on the situation.
The general formulas are:
dU=dQ+dW
dU=TdS-PdV
dH=TdS+VdP

I think you would use ΔH=ΔQ for a quasi-static, constant-pressure process.
And you would use ΔU=-ΔW for an adiabatic process.

I believe both processes apply in a steam turbine cycle.
 
I need to calculate the amount of water condensed from a DX cooling coil per hour given the size of the expansion coil (the total condensing surface area), the incoming air temperature, the amount of air flow from the fan, the BTU capacity of the compressor and the incoming air humidity. There are lots of condenser calculators around but they all need the air flow and incoming and outgoing humidity and then give a total volume of condensed water but I need more than that. The size of the...
Thread 'Why work is PdV and not (P+dP)dV in an isothermal process?'
Let's say we have a cylinder of volume V1 with a frictionless movable piston and some gas trapped inside with pressure P1 and temperature T1. On top of the piston lay some small pebbles that add weight and essentially create the pressure P1. Also the system is inside a reservoir of water that keeps its temperature constant at T1. The system is in equilibrium at V1, P1, T1. Now let's say i put another very small pebble on top of the piston (0,00001kg) and after some seconds the system...
Back
Top