Second order approximation in time independent perturbaton theory

In summary, second order approximation in time independent perturbation theory is a method used in quantum mechanics to make approximations to the energy levels and wavefunctions of a system. It involves expanding the system's Hamiltonian and using perturbation theory to solve for corrections. The difference between first and second order approximation is that the latter takes into account both first and second order terms, allowing for a more accurate calculation. Second order approximation is calculated by solving second order perturbation equations, and is necessary when the perturbation is not small enough for first order approximation to be accurate. However, there are limitations to second order approximation, such as the assumption of small perturbations and its applicability to highly degenerate energy levels.
  • #1
paweld
255
0
Is there any physical reason why second order approximation to
ground state in time independent perturbation theory is always
negative. I know how to prove it mathematicly but I wonder
whether one may justify it using only physical arguments.
 
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  • #2
because the energy of the tials functions are always more more than the ground state
 
  • #3


The second order approximation in time independent perturbation theory is always negative due to the nature of the perturbation itself. In this theory, a small perturbation is applied to a system that is initially in its ground state. This perturbation causes the system to deviate from its ground state, resulting in an energy shift. The second order approximation takes into account the second order effect of this perturbation on the energy of the system.

Physically, this second order effect results in a decrease in the energy of the system. This can be understood by considering the perturbation as a disturbance that disrupts the equilibrium of the system. As the system tries to return to its ground state, it must release energy in order to do so. This energy release is manifested in the negative value of the second order approximation.

Additionally, the perturbation itself is assumed to be small, which means that the second order effect is even smaller. This further justifies the negative value of the second order approximation, as it represents a small decrease in energy due to the perturbation.

In summary, the physical reason for the negative value of the second order approximation in time independent perturbation theory is due to the nature of the perturbation and its effect on the energy of the system.
 

What is second order approximation in time independent perturbation theory?

Second order approximation in time independent perturbation theory is a method used in quantum mechanics to make approximations to the energy levels and wavefunctions of a system that is subject to a small perturbation. It involves expanding the system's Hamiltonian in terms of a small parameter and using perturbation theory to solve for the corrections to the energy levels and wavefunctions.

What is the difference between first and second order approximation?

In first order approximation, only the first order term of the perturbation expansion is considered, while in second order approximation, both the first and second order terms are taken into account. This allows for a more accurate calculation of the energy levels and wavefunctions of a system.

How is second order approximation calculated?

The second order approximation is calculated by solving the second order perturbation equations, which involve integrating the second order terms of the perturbation expansion. This can be done numerically or analytically, depending on the complexity of the system.

When is second order approximation necessary?

Second order approximation is necessary when the perturbation to a system is not small enough to be accurately described by first order approximation. This is often the case in more complex systems, where the perturbation may have a significant impact on the energy levels and wavefunctions.

What are the limitations of second order approximation?

Second order approximation is based on the assumption that the perturbation to the system is small. If this is not the case, then higher order approximations may be necessary for accurate calculations. Additionally, second order approximation may not be applicable to systems with highly degenerate energy levels.

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