Solid State: Diffraction Conditions

In summary, the diffraction condition 2\vec{k} \cdot \vec{G}=G^2 can be written as 2k\sin{\theta}=n\lambda, where d_{hkl} is the spacing between adjacent planes of (hkl) index and d is the spacing between the same plane in successive unit cells. This is known as the Bragg law and it relates the angle of incidence, wavelength, and plane spacing for a diffraction pattern.
  • #1
Itserpol
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In my Solid State course we've reached the topic of crystal diffraction and reciprocal lattices. I haven't had any problems so far, but I've hit a little snag in understanding how the diffraction condition [tex]2\vec{k} \cdot \vec{G}=G^2[/tex] is equivalent to the Bragg law [tex]2d\sin{\theta}=n\lambda[/tex].

In the textbook (Introduction to Solid State Physics - Kittel 8th Ed.), the math is as follows:

  1. The reciprocal lattice vector [tex]\vec{G}=h\vec{b}_1+k\vec{b}_2+l\vec{b}_3[/tex] is normal to the lattice plane given by the indices [tex](hkl)[/tex].
  2. The spacing between these planes is [tex]d_{hkl}=\tfrac{1}{h}\hat{n}\cdot\vec{a}_1=\tfrac{1}{Gh}\vec{G}\cdot\vec{a}_1=\tfrac{2\pi}{G}[/tex] where [tex]\vec{a}_1[/tex] is a primitive axis for the direct lattice.
  3. The diffraction condition [tex]2\vec{k} \cdot \vec{G}=G^2[/tex] can then be written as [tex]2k\sin{\theta}=2(\tfrac{2\pi}{\lambda})\sin{\theta}=\tfrac{2\pi}{d_{hkl}} \Rightarrow 2d_{hkl}\sin{\theta}=\lambda[/tex]. Here, [tex]\theta[/tex] is the angle between [tex]\vec{k}[/tex] and the plane [tex](hkl)[/tex], not between [tex]\vec{k}[/tex] and [tex]\vec{G}[/tex].
  4. Somehow [tex]d_{hkl}=\tfrac{d}{n}[/tex], so this becomes [tex]2d\sin{\theta}=n\lambda[/tex] which is just the Bragg law.

Now, most of this I understand. The only things I don't get are why the lattice plane spacing [tex]d_{hkl}[/tex] is equal to [tex]\tfrac{1}{h}\hat{n}\cdot\vec{a}_1[/tex] and what the relationship [tex]d_{hkl}=\tfrac{d}{n}[/tex] means. What's the difference in physical meaning between [tex]d_{hkl}[/tex] and [tex]d[/tex]?
 
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  • #2
The relationship d_{hkl}=\tfrac{1}{h}\hat{n}\cdot\vec{a}_1 is due to the fact that the reciprocal lattice vector \vec{G} is normal to the lattice plane given by the indices (hkl). This means that the lattice plane spacing d_{hkl} is equal to the magnitude of the projection of \vec{a}_1 onto \vec{G}, which is equal to \tfrac{1}{h}\hat{n}\cdot\vec{a}_1, where \hat{n} is a unit vector normal to \vec{G}.The relationship d_{hkl}=\tfrac{d}{n} means that for any given lattice plane (hkl), the spacing between successive planes is equal to the spacing between the same plane in successive unit cells, divided by the number of unit cells in that plane. That is, the distance between two adjacent planes of (hkl) index is equal to n times the distance between the same plane in successive unit cells. The physical meaning here is that the distance between two adjacent planes of (hkl) index is equal to the average distance between the same plane in successive unit cells.
 

1. What is the definition of solid state diffraction?

Solid state diffraction refers to the scattering of X-rays or neutrons by the regularly arranged atoms in a solid material, resulting in a diffraction pattern that can be used to determine the crystal structure and properties of the material.

2. What are the three main diffraction conditions for solid state materials?

The three main diffraction conditions are the Laue condition, Bragg condition, and Ewald construction. These conditions relate the wavelength of the incident radiation, the crystal lattice spacing, and the angle of diffraction to determine the positions and intensities of the diffracted beams.

3. How does the crystal structure affect the diffraction pattern?

The crystal structure of a material determines the arrangement of atoms in the lattice, which in turn affects the spacing between planes of atoms. The diffraction pattern is a result of the interaction between incident radiation and the crystal lattice, so changes in crystal structure will result in changes in the diffraction pattern.

4. What is the difference between powder and single crystal diffraction?

Powder diffraction involves scattering from polycrystalline materials, where the crystal orientations are randomly distributed. Single crystal diffraction, on the other hand, involves scattering from a single crystal, where the diffraction pattern is a result of the ordered arrangement of atoms in the lattice.

5. What are common applications of solid state diffraction?

Solid state diffraction is used in a variety of fields, including materials science, geology, chemistry, and physics. It is commonly used to determine the crystal structure and properties of materials, such as minerals, metals, and pharmaceuticals. It is also used in the development and quality control of materials in industries such as aerospace and electronics.

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