Solve Fe(NH4)2(SO4)2. xH2O: Calculate Moles of Iron & Sulfate

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To determine the value of x in Fe(NH4)2(SO4)2·xH2O, the discussion focuses on calculating the moles of sulfate and iron in a 0.982g sample. The sample was treated with BaCl2, resulting in a precipitate of BaSO4 weighing 1.17g. For part (a), the calculation of moles of sulfate yields 0.00501 moles, which is derived from the mass of BaSO4 formed, indicating the amount of sulfate in the original sample. In part (b), the moles of iron calculated is 0.00250, which is half the amount of sulfate, reflecting the stoichiometry of the compound where each formula unit contains two iron ions. The discussion also highlights previous attempts to solve the problem, with some hints being deemed incorrect, but ultimately leading to a better understanding of the calculations involved.
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Hi, I would be very grateful if anyone could show me how to answer the following question:

The value of x in Fe(NH4)2(SO4)2. xH2 O can be found by determining the amount in moles of sulfate in the compound.
A 0.982g sample was dissolved in water and excess BaCl2 (aq) was added.
The precipitate of BaSO4 was separated and dried and found to weigh 1.17g.

(a) Calculate the amount, in moles, of sulfate in the 0.982g sample of Fe(NH4)2(SO4)2. xH2O

(according the the answers it's 0.00501 which I do not understand)

(b) Calculate the amount, in moles, of iron in the 0.982g sample of Fe(NH4)2(SO4)2. xH2O

(apparently the answer is 0.00250 which is half of the previous answer - why?!)

Thanks in advance.
 
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You have asked the same question at CF and you were already given hints there, nobody is going to solve the question for you.
 
Borek said:
You have asked the same question at CF and you were already given hints there, nobody is going to solve the question for you.

The hints were wrong though. Its ok though, I understand it now.
 
CSG18 said:
The hints were wrong though.

They were perfect.
 
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