Statistical physics. Density matrix

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SUMMARY

The discussion centers on the formulation of the density matrix for a system governed by the Hamiltonian ##\hat{H}=-\gamma B_z \hat{S}_z##. The density matrix is defined using the canonical ensemble as ##\hat{\rho}=\frac{1}{Tr(e^{-\beta \hat{H}})}e^{-\beta \hat{H}}##. It is emphasized that the density matrix is contingent upon the state of the system, necessitating additional information about the particle's spin to apply the correct definition. The implication is that the problem assumes thermal equilibrium conditions.

PREREQUISITES
  • Understanding of Hamiltonian mechanics and its representation in quantum systems.
  • Familiarity with the concept of density matrices in statistical mechanics.
  • Knowledge of canonical ensembles and their application in thermodynamics.
  • Basic quantum mechanics, particularly regarding particle spin states.
NEXT STEPS
  • Study the derivation of the density matrix in the context of quantum statistical mechanics.
  • Learn about the implications of different spin values on the density matrix formulation.
  • Explore the concept of thermal equilibrium and its significance in statistical physics.
  • Investigate the role of the trace operation in quantum mechanics and its applications in density matrices.
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Students and researchers in physics, particularly those focused on quantum mechanics and statistical physics, as well as anyone studying the properties of systems in thermal equilibrium.

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Homework Statement


A system is subject to Hamiltonian ##\hat{H}=-\gamma B_z \hat{S}_z##. Write down the density matrix.[/B]

Homework Equations


For canonical ensemble
##\hat{\rho}=\frac{1}{Tr(e^{-\beta \hat{H}})}e^{-\beta \hat{H}}##

In general ##\rho=\sum_m |\psi_m\rangle \langle \psi_m|##

The Attempt at a Solution


How to know which definition of density matrix to use? Thanks.
 
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The density matrix (statistical operator) is, of course, not determined by just giving the Hamiltonian but by the state of the system, because the statistical operator describes the state of the system. So there must be something missing from the problem statement or it is implied to consider a system in thermal equilibrium and to use the canonical ensemble. In the latter case it's not that difficult, if (again some information missing in the problem statement!) you know what spin your particle, i.e., ##s \in \{0,1/2,1,\ldots \}##.
 

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