Surprise? Entropy changes for systems in a canonical state

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maajdl
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Every year since the 90's I come back to some of my pet topics in physics, like statistical physics.
This time it was the reading of a Wikipedia article on entropy that surprised me.
The derivation of the second law from the Gibbs entropy was unknown to me.
I didn't know how heat, how change of internal energy, and how work can be identified from the equations below:

6e42d8b7fd3830084141f9d0cb4f3d9715881171
edbcfce7e6e6c915bc211eb40239d5cefa9ce6e3
f69390136af8271cf1b44410b38ae32308b00e6b

or

df63971dc42a5cfffe90afe9a0d043f63fd59fa8


Not only is this derivation very simple but it also clarifies the meaning of heat and work from a statistical point of view.

I would like to know:

- if you were aware of this argument
- when/how you learned it
- how far it could be traced back in time (Gibbs maybe)
- if you know other references that mention this argument and discuss it further

Thanks to share
 
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