Draw a Venn diagram with sets A and B. Shade in the area "that belongs to either A or B, but not both."
Then, I'd say just make sure you first know exactly what (a) means, i.e., what is A\B and B\A. You should easily be able to see that the definition of D in (a) is the same as the more intuitive definition "either A or B, but not both."
Finally, you should write a quick formal proof that shows the definition in (a) is the same as that in (b).
i.e, prove that (A \ B) U (B \ A) = (A U B) \ (A [tex]\cap[/tex] B).
Since you're new to all of this, don't skip steps. Take care of the details!