Temperature analog of free energy

AI Thread Summary
The discussion focuses on the Gibbs energy, which indicates spontaneity in thermodynamic processes at constant pressure, and the Helmholtz energy, applicable under constant volume. A query arises about an energy measure for spontaneity at constant temperature, leading to suggestions to explore the concept of chemical potential. The chemical potential is identified as related to the partial molar Gibbs energy in multi-component systems. The conversation concludes by clarifying that Gibbs energy is minimized at constant pressure and temperature, while Helmholtz energy is minimized at constant volume and temperature.
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The Gibbs energy is used to determine the spontaneity of a thermodynamic process under isobaric conditions.

The Helmholtz energy is used to determine the spontaneity of a thermodynamic process under isovolumetric conditions.

I was curious: is there an energy used to determine the spontaneity of a thermodynamic process under isothermal conditions?

Thanks.

BiP
 
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I suggest you look up

'The Chemical Potential'

Google has lots of references.
 
Studiot said:
I suggest you look up

'The Chemical Potential'

Google has lots of references.

Isn't the chemical potential just equal to the partial molar Gibbs energy of a multi-component system? How is that related to my question?

BiP
 
Well, Gibbs energy is minimal under constant pressure AND temperature, and Helmholtz under constant volume and temperature. So, there...
 
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