Transition in magnetic refrigeration

AI Thread Summary
The discussion focuses on calculating the temperature change of a thermally isolated piece of Gd as the magnetic field is reduced from 1.2T to 0.8T at 300K. The relevant equation involves the derivative of magnetization with respect to temperature, which participants are trying to apply correctly. The graph provided shows the relationship between magnetization and temperature, and it is assumed that this relationship remains consistent within the specified magnetic field range. There is uncertainty about deriving the functional form of the temperature derivative from the graph. Participants are seeking hints to guide them in solving the problem effectively.
CAF123
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Homework Statement


The graph below (see attached) shows the measured magnetization against temperature at room pressure for the material Gd and for another material for use in a magnetic refrigerator at room temperature.

1)Calculate the expected change of temperature of a thermally isolated piece of Gd when the field in which it is located slowly reduced from an induction of H1 = 1.2T to H2 = 0.8T starting at a temperature 300K. You may assume that the M versus T curve does not change appreciably with H for H in the range 0.8-1.2T. Additionally, assume that the molar specific heat capacity of Gd is Cp = 3R J/K/mol of atoms, independent of temperature and field, The formula mass of Gd is 157.25g/mol.

Homework Equations


Derived in earlier part: $$dT = - \frac{T}{C_{p,H}} \left(\frac{\partial \mathbb{M}(T,H)}{\partial T}\right)_{H,P} dH$$

The Attempt at a Solution


I think I have to use the above equation derived in an earlier 'show that'. The graph attached shows M/ρ vs T which is equivalent to ##\mathbb{M} / m## since we are also to assume the magnetization,M, is related ##\mathbb{M} = MV##.
So, $$\frac{\partial \mathbb{M}/m}{\partial T} = \frac{1}{m} \frac{\partial \mathbb{M}}{\partial T} + \mathbb{M} \frac{\partial}{\partial T} \frac{1}{m},$$ where ##\partial \mathbb{M}/m / \partial T## is the slope of the given graph.

Since it says the curve does not change appreciably, I think this means the graph has a constant gradient in the particular interval. But I am not sure how to obtain a functional form of ##\partial \mathbb{M}/\partial T##. I can relate this to a Maxwell relation, but I don't think this helps.


Many thanks.
 

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