Understanding Benzene: Hybrid Structures vs. Superposition Explained

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Discussion Overview

The discussion centers around the concepts of hybrid structures and superposition in the context of benzene, exploring whether these two concepts are equivalent or distinct in molecular chemistry.

Discussion Character

  • Conceptual clarification, Debate/contested

Main Points Raised

  • One participant questions whether hybrid structures and superpositions are the same, specifically in relation to benzene.
  • Another participant asserts that resonance hybrids represent real molecular orbitals and are not superpositions of molecular orbitals.
  • A subsequent post inquires if benzene possesses both a superposition and a hybrid structure.
  • Another participant notes that superpositions of energy eigenstates typically arise during electronic excitation of a molecule, such as when interacting with light.

Areas of Agreement / Disagreement

Participants express differing views on the relationship between hybrid structures and superpositions, indicating that the discussion remains unresolved.

Contextual Notes

Some claims depend on specific definitions of hybrid structures and superpositions, which may not be universally agreed upon. The discussion also touches on the conditions under which superpositions are relevant.

Parnpuu
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Question: Is a hybrid structure and a superposition the same thing? (I'm interested in the case of benzene)

Read many sources but they were contradictory..

Please help!
Thanks!
 
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Ok, but does benzene have a superposition as well as a hybrid structure?
 
Superpositions of energy eigenstates normally only come into play when you electronically excite a molecule (for example, when the molecule is interacting with light).
 

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