Validity of the sudden approximation

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Homework Statement



The Schrodinger equation is given by

$$i\hbar\ \frac{\partial}{\partial t}\ \mathcal{U}(t,t_{0})=H\ \mathcal{U}(t,t_{0}),$$

where ##\mathcal{U}(t,t_{0})## is the time evolution operator for evolution of some physical state ##|\psi\rangle## from ##t_0## to ##t##.Rewriting time ##t## as ##t=s\ T##, where ##s## is a dimensionless parameter and ##T## is a time scale, the Schrodinger equation becomes as

$$i\ \frac{\partial}{\partial s}\ \mathcal{U}(t,t_{0})=\frac{H}{\hbar/T}\ \mathcal{U}(t,t_{0})=\frac{H}{\hbar\ \Omega}\ \mathcal{U}(t,t_{0}),$$

where ##\Omega \equiv 1/T##.

In the sudden approximation, ##T \rightarrow 0##, which means that ##\hbar\ \Omega \gg H##. 1. Are we allowed to redefine ##H## by adding or subtracting an arbitrary constant?
2. How does this introduce some overall phase factor in the state vectors?
3. Why does this imply that ##\mathcal{U}(t,t_{0})\rightarrow 1## as ##t\rightarrow 0##?
4. How does this prove the validity of the sudden approximation?

Homework Equations



The Attempt at a Solution



1. I think that we are allowed to redfine ##H## by adding or subtracting an arbitrary constant, because ##H=T-V## and the potential ##V## can be redefined by adding or subtracting an arbitrary constant without changing the physical system.

What do you think?
 
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Yes, you are allowed to redefine the Hamiltonian by addition of a constant. Note however that H=T+V, unless you are using an unusual definition of V.
You also have to take in mind that ##\hbar \Omega \gg H## is meaningless as you are comparing an operator with a number. As H usually is unbound, the sudden approximation never holds for all states and convergence is non-uniform.
 
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