Vinegar & Soda Water: Strange Result?

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Mixing vinegar with soda water, which contains sodium carbonate and sodium silicate, resulted in the formation of insoluble white pieces. This outcome is attributed to the interaction between vinegar's acetic acid and sodium silicate, potentially leading to the formation of silicate acid, known for its poor solubility in water. The discussion emphasizes the importance of using pure chemicals for neutralization to avoid unexpected side reactions. It suggests that the observed white precipitates could be silicate acid and recommends testing the solution with a base to determine if the precipitates dissolve, confirming their identity.
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Recently, I mixed vinegar and soda water together in a plate, but the result was confusing. Since soda water contain sodium silicate and sodium ash, the result should be soluble, as sodium salts always dissolve in the water. However, in the experiment, I get some white pieces which can't dissolve in the water. What is it?
 
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Vinegar has some preservative compounds, I think the white pieces come from it. You wanted to do a neutralization, I suppose, I recommend that you do it with real chemicals to avoid side reactions (like those white pieces you saw in your experiment). You may be right about sodium salts' solubility, but consider that vinegar acid may produce silicate acid, which is poorly soluble in water.
 
scilover89 said:
Recently, I mixed vinegar and soda water together in a plate, but the result was confusing. Since soda water contain sodium silicate and sodium ash, the result should be soluble, as sodium salts always dissolve in the water. However, in the experiment, I get some white pieces which can't dissolve in the water. What is it?

Hmmm...by "soda water," what do you mean? Normally, that refers to a solution of CO2 in H2O, which is carbonic acid (a very weak acid). You add a little flavoring to make a carbonated beverage.
 
pack_rat2 said:
Hmmm...by "soda water," what do you mean? Normally, that refers to a solution of CO2 in H2O, which is carbonic acid (a very weak acid). You add a little flavoring to make a carbonated beverage.
I meant the solution of sodium carbonate and sodium silicate.
 
chem_tr said:
Vinegar has some preservative compounds, I think the white pieces come from it. You wanted to do a neutralization, I suppose, I recommend that you do it with real chemicals to avoid side reactions (like those white pieces you saw in your experiment). You may be right about sodium salts' solubility, but consider that vinegar acid may produce silicate acid, which is poorly soluble in water.
Yeah, the solution did contain sodium silicate as you predict earlier. So what could be the side effect chemical equation that produced silicate acid?
Anyway, thanks for your advice.
 
It is clear I think; silicate acid is very sparingly soluble in water, so white precipitates will form. Maybe the ones you saw were just silicate acid, who knows? You may try treating this solution with a base, and report if these precipitates disappear. Then you can conclude that this is probably silicate acid.
 
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