What Are Eigenstates and Their Role in Quantum Mechanics?

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I've read the chapter but it hasn't helped. Eigenstates are states with a definite amount of energy independent on time? and then any other state is a linear combination of the eigenstates, with some Cn acting as a weighting factor...is there a limitation on what the Cn's can be? otherwise, wouldn't non-stationary states be unquantized?
 
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In fact, the |c_n|^2 are the probabilities of measuring the energy value E_n. Remember that quantum mechanics assumes that the wave function collapses to an energy-eigenstate when the energy is measured, so the measured energy is still quantized.

This "collapse" means the wavefunction is

\Psi = \sum \limits _n c_n \varphi_n before the energy is measured, where the |c_n|^2 say how probable it is to measure energy E_n.

Right after the measurement of energy E_n, the wavefunction collapses to

\Psi = \varphi_n.
 
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