What are the allowed transitions in the pure rotational spectra of CO2 molecule?

AI Thread Summary
The discussion centers on the allowed transitions in the pure rotational spectra of the CO2 molecule, specifically the selection rule ΔJ = ±1. A point of contention arises regarding the professor's claim that odd values of J are not allowed, leading to the conclusion that only even transitions (0 <-> 1, 2 <-> 3, etc.) are valid. This contradicts the typical understanding of rotational transitions, where odd states should be populated. The original poster sought clarification on the accuracy of these statements and confirmed they found the answer independently. The conversation highlights confusion surrounding quantum mechanical calculations and the implications for molecular spectroscopy.
Shivpal
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I know that the selection rule is :
\DeltaJ = +/- 1

but our prof said that according to some quantum mechanical calculations the odd values of J are not allowed. So, the allowed transitions are :
J 0 <-> 1 ; 2 <-> 3 ; 4 <-> 5... as the odd(1,3,5..) states will not be populated(hence contradicting his own statement)... and no transitions as J 1 -> 2 ; 3 -> 4 ...

I raised the question in the class but he seemed a bit more confused after my question.

Can anyone confirm the authentication of his statements. And Please tell me what is right and what is wrong. Thanx.
 
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...I checked everything on the internet (starting with wiki), and then asked the question here...by the way i got the answer...thanks for showing concern...
 
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