What causes absence of mesomeric interaction in benzoic acids?

  • Thread starter Thread starter Vectorcrust
  • Start date Start date
  • Tags Tags
    Acids
AI Thread Summary
The discussion centers on the lack of mesomeric interaction between the π-electrons of the aromatic ring and the π-electrons of the carbonyl group in benzoic acids. The primary reason identified is that the positive charge resulting from the dissociation of the proton is fully borne by the proton itself, rather than being shared with the carbonyl carbon. Additionally, it is noted that there are no valid resonance structures that satisfy the octet rule, further explaining the absence of significant resonance stabilization in this context.
Vectorcrust
Messages
5
Reaction score
0
Why there is no mesomeric interaction between \pi-electrons of aromatic ring and \pi-electrons of carbonyl group in benzoic acids?
 
Chemistry news on Phys.org
I would think it was because the postive charge was bourne fully by the dissociated proton rather than the carbonyl carbon attached to the aromatic ring.
 
There are no valid resonance structures satisfying the octet rule.
 
It seems like a simple enough question: what is the solubility of epsom salt in water at 20°C? A graph or table showing how it varies with temperature would be a bonus. But upon searching the internet I have been unable to determine this with confidence. Wikipedia gives the value of 113g/100ml. But other sources disagree and I can't find a definitive source for the information. I even asked chatgpt but it couldn't be sure either. I thought, naively, that this would be easy to look up without...
I was introduced to the Octet Rule recently and make me wonder, why does 8 valence electrons or a full p orbital always make an element inert? What is so special with a full p orbital? Like take Calcium for an example, its outer orbital is filled but its only the s orbital thats filled so its still reactive not so much as the Alkaline metals but still pretty reactive. Can someone explain it to me? Thanks!!
Back
Top