The discussion centers on the lack of mesomeric interaction between the π-electrons of the aromatic ring and the π-electrons of the carbonyl group in benzoic acids. The primary reason identified is that the positive charge resulting from the dissociation of the proton is fully borne by the proton itself, rather than being shared with the carbonyl carbon. Additionally, it is noted that there are no valid resonance structures that satisfy the octet rule, further explaining the absence of significant resonance stabilization in this context.
#1
Vectorcrust
5
0
Why there is no mesomeric interaction between \pi-electrons of aromatic ring and \pi-electrons of carbonyl group in benzoic acids?
I would think it was because the postive charge was bourne fully by the dissociated proton rather than the carbonyl carbon attached to the aromatic ring.
#3
asym
21
0
There are no valid resonance structures satisfying the octet rule.
Do the published values of Enthalpy include the work done against a constant pressure, e.g., the atmosphere? (I am not a chemist). I am reviewing enthalpy and entropy as part of the statistical mechanics applied to transistors. I assume, from my reading, that the work done would mostly apply to reactions involving gasses.
It seems like a simple enough question: what is the solubility of epsom salt in water at 20°C? A graph or table showing how it varies with temperature would be a bonus. But upon searching the internet I have been unable to determine this with confidence. Wikipedia gives the value of 113g/100ml. But other sources disagree and I can't find a definitive source for the information. I even asked chatgpt but it couldn't be sure either. I thought, naively, that this would be easy to look up without...
I was introduced to the Octet Rule recently and make me wonder, why does 8 valence electrons or a full p orbital always make an element inert?
What is so special with a full p orbital?
Like take Calcium for an example, its outer orbital is filled but its only the s orbital thats filled so its still reactive not so much as the Alkaline metals but still pretty reactive.
Can someone explain it to me?
Thanks!!