What do the blue and pink color of the rust indicator shown mean?

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The discussion centers on the interpretation of color changes in a rust indicator, specifically the mixture of potassium hexacyanoferrate(III) and phenolphthalein, when applied to an iron nail. The blue color indicates the presence of Fe2+ ions, signifying that rusting has occurred, while the pink color indicates the presence of hydroxide ions, suggesting potential rust formation. The pink area does not indicate active rusting but rather the conditions leading to rust, as hydroxide ions are produced prior to rust formation. Participants clarify that both ions are generated simultaneously during the rusting process, reflecting different half-reactions occurring in the presence of a conductor.
Green18
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Hello, everyone.
What do the blue and pink color the rust indicator shown mean?

Let say, the mixture of potassium hexacyanoferrate(III) and phenolphthalein is the rust indicator. And we use to detect the rusting of an iron nail. And the result is: the tip, head region of the nail appear blue color; the straight region appears pink color.
Is that the blue region shows Fe2+ ions formed? And, the pink shows hydrogen ions present?

But, even it shows these ions are present, what does it mean? The blue area is rusting? And the pink area no rusting?

Confused :( please help!
 
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Green18 said:
Is that the blue region shows Fe2+ ions formed?

Yes.

And, the pink shows hydrogen ions present?

No, quite the opposite - it shows where the amount of H+ is small.

But, even it shows these ions are present, what does it mean?

Where do they come from?
 
Thanks for replying.
Sorry, my bad. That is a typo.
I should write 'hydroxide ions' ,
the pink area shows the presence of HYDROXIDE ions .
But, i don't get it, even hydroxide ions is produced, what does it mean? Does it mean the pink area part is rusting?
 
Last edited:
No, it contains possible rusting product.
 
Borek said:
No, it contains possible rusting product.

Thanks again.
So simply speaking, the blue area means the rusting has already taken place/ the rust is formed . And the pink area means it is going to form rust (coz hydroxide ions are produced before rust is formed.)
Am i right? :)
 
I think both ions are produced at the same time, they just show where different half reactions occur (they don't have to go in teh same place, as long as there is conductor present).
 
Borek said:
I think both ions are produced at the same time, they just show where different half reactions occur (they don't have to go in teh same place, as long as there is conductor present).
Thank you
 
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