What fraction of molecules in an ideal gas have velocites between φ1 & φ2 and θ1 & θ2

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Homework Help Overview

The problem involves determining the fraction of molecules in an ideal gas that have velocities within specific angular ranges defined by φ and θ. The context is rooted in statistical mechanics and the Maxwell-Boltzmann distribution.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • The original poster questions the geometric interpretation of the problem. Some participants suggest using the Maxwell-Boltzmann distribution to relate the angular parameters to a fraction of the spherical surface area.

Discussion Status

Participants are exploring the relationship between the angles and the fraction of molecules, with one providing a mathematical expression for the fraction. There is a request for further resources and derivations, indicating a lack of comprehensive understanding of the topic.

Contextual Notes

There is mention of the absence of relevant material in lectures and textbooks, which may affect the participants' ability to fully grasp the concepts involved.

Phyrrus
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Homework Statement



Approximately what fraction of molecules of a gas (assumed ideal) have velocities for
which the angle φ lies between 29.5° and 30.5°, while θ lies between 44.5° and 45.5°?

Homework Equations





The Attempt at a Solution



What does the question even mean geomtrically?
 
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Since the Maxwell Boltzmann distribution for a free diluite gas depend only on the modulus of the velocity, the fraction of the particles that have velocity between the angles defined by [itex]\phi_1[/itex] and [itex]\phi_2[/itex], [itex]\theta_1[/itex] and [itex]\theta_2[/itex] is simply the fraction of the area of part of the spherical surface determined by those parameters and the surface of the sphere; namely

fraction= [itex]\frac{1}{4\pi}(\phi_2-\phi_1)([/itex]cos[itex](\theta_1)-[/itex]cos[itex](\theta_2))[/itex]

all the angles are expressed in radiants.
 


Thanks mate, is there somewhere I could get a detail analysis and derivation of this, because it wasn't in any lectures and isn't in my text at all.
 


You are welcome; the best place where one can study all this stuff at the introductory level is Huang's textbook "Statistical Mechanics".
f.
 

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