What is the atomic spacing D of this crystal?

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The discussion centers on calculating the atomic spacing D of a crystal with a hexagonal structure using X-ray diffraction data. The Bragg condition is applied, leading to an initial calculation of D as 0.16 nm based on the X-ray wavelength of 0.10 nm and specific angles. However, it is noted that this value represents the distance between crystal planes, not atomic spacing. To find the atomic spacing, the crystal geometry must be considered, indicating that the initial approach may not fully account for the hexagonal structure. The final takeaway emphasizes the need to adjust calculations to reflect the specific geometry of the crystal.
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Homework Statement


X rays with wavelength 0.10 nm are incident on a crystal with a hexagonal crystal structure. The x-ray diffraction spectrum is shown in the figure.

Figure:
knight_Figure_24_40.jpg




What is the atomic spacing D of this crystal? (in nanometers)



Homework Equations



The Bragg condition:
2*D*cos(theta)=m*lamda where, m=1,2,3...


The Attempt at a Solution



(m+1)/(m) ==> cos(50.1)/cos(71.3) = (2/1)

(m+1)/(m)==> cos(15.8)/cos(71.3) = (3/1)

D=(2*lamda)/(2*cos(theta_2)==> (lamda)/cos(theta_2)==> (0.10nm)/cos(50.1)=0.16nm

I just followed a similair example in the book. Maybe I'm getting it wrong because I'm not factoring anything in about the hexagonal shape in my math? *Note: this is a challange problem.
 
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(Note to others: OP is using ##\theta## defined relative to the normal of the plane, rather than parallel, hence the appearance of the cosine rather than the more usual sine in the Bragg condition.)

OP, you have correctly determined that the distance between the crystal planes is 0.16 nm. However, the problem is looking for the distance between atoms, so you’ll need to use the crystal geometry to solve for D.
 
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