What is the Crystal Structure of Aluminum and its Bonding Patterns?

AI Thread Summary
The discussion centers on creating a model of pure aluminum using styrofoam balls and toothpicks, specifically focusing on the face-centered cubic (FCC) structure. Participants clarify that pure aluminum does not form distinct bonds like covalent or ionic compounds, as it is a metal. Instead, the FCC structure consists of aluminum atoms positioned at the corners of a cube and one at the center of each face. The stacking of layers is crucial, with the correct pattern being ABCABC for FCC lattices, rather than identical layers. This distinction is important for accurately representing the atomic arrangement in the model, particularly when visualizing the close-packed planes.
LABQT
For my project, I am creating a pure aluminum model with styro foam balls and toothpicks. I know this structure is a "face-centered cubic". However, I don't know the bonding angles and what kind of bonding shape (tetrahedral, octahedral ...), I need the information for the write-up. Can someone help please.
 
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Er... being a metal, I wouldn't think pure aluminium would really form any distinct bonds that you can represent. Most models of metal crystals are simply layers of balls glued onto each other.

To visualise a face centred cubic structure, picture a cube with eight aluminium particles, one on each vertex. At the centre of each face, there is an additional particle. Repeat pattern many times, et viola.

eg.

Code:
Layer 1:

O   O   O
  O   O
O   O   O
  O   O
O   O   O

Layer  2:

  O   O
O   O   O
  O   O
O   O   O
  O   O

Layer 3:


O   O   O
  O   O
O   O   O
  O   O
O   O   O

Don't trust my crappy diagram so much though.
 
Last edited:
Thanks for the reply. Now I understand.
 
I think the third layer is wrong.
 
adianadiadi said:
I think the third layer is wrong.

The third layer is identical to the first layer. And the fourth would be identical to the second and so on. It is basically the way in which the atoms stack together the best. If all the layers were identical there would be too much empty space between atoms.
 
But In aluminium, there is FCC lattice. That means, the third layer must be different also. It has ABCABC-----pattern and not ABAB_____ pattern
 
adianadiadi said:
But In aluminium, there is FCC lattice. That means, the third layer must be different also. It has ABCABC-----pattern and not ABAB_____ pattern

This is correct if one is drawing the close-packed {111} planes. But FZ+ drew the {100} planes correctly; every other {100} plane is identical.
 
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