ghostanime2001
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Enthalpy of NaOH(s) --> NaOH(g)
Given:
1. Na_{(s)} \rightarrow Na_{(g)} \Delta H = 109 kJ
2. \Delta H^{\circ}_{diss} = 251\:kJ\:for\:O_{2}
3. \Delta H^{\circ}_{diss} = 435\:kJ\:for\<img src="/styles/physicsforums/xenforo/smilies/arghh.png" class="smilie" loading="lazy" alt=":H" title="Gah! :H" data-shortname=":H" />_{2}
4. \Delta H^{\circ}_{diss} = 465\:kJ\:for\:O-H
5. \Delta H^{\circ}_{diss} = 255\:kJ\:for\:Na-O
6. \Delta H_{soln} = -46\:kJ\:for\:NaOH_{(s)}
7. \Delta H^{\circ}_{f} = -427\:kJ\:for\:NaOH_{(s)}
Predict \Delta H for NaOH_{(s)} \rightarrow NaOH_{(g)} ?
see above
I understand the standard states of all substances for #1-3 but I am unsure of #4,5,7. I don't understand what the standard states are for #4,5 (both reactants and products). I don't understand what the physical state of sodium is for #7 (is it solid or gas ?). Also how will the aqueous ions produced from dissociation of sodium hydroxide in #6 cancel out ? and how will covalent bonds of Na-O or O-H as reactants cancel out ?
Thanks! :)
Homework Statement
Given:
1. Na_{(s)} \rightarrow Na_{(g)} \Delta H = 109 kJ
2. \Delta H^{\circ}_{diss} = 251\:kJ\:for\:O_{2}
3. \Delta H^{\circ}_{diss} = 435\:kJ\:for\<img src="/styles/physicsforums/xenforo/smilies/arghh.png" class="smilie" loading="lazy" alt=":H" title="Gah! :H" data-shortname=":H" />_{2}
4. \Delta H^{\circ}_{diss} = 465\:kJ\:for\:O-H
5. \Delta H^{\circ}_{diss} = 255\:kJ\:for\:Na-O
6. \Delta H_{soln} = -46\:kJ\:for\:NaOH_{(s)}
7. \Delta H^{\circ}_{f} = -427\:kJ\:for\:NaOH_{(s)}
Predict \Delta H for NaOH_{(s)} \rightarrow NaOH_{(g)} ?
Homework Equations
see above
The Attempt at a Solution
I understand the standard states of all substances for #1-3 but I am unsure of #4,5,7. I don't understand what the standard states are for #4,5 (both reactants and products). I don't understand what the physical state of sodium is for #7 (is it solid or gas ?). Also how will the aqueous ions produced from dissociation of sodium hydroxide in #6 cancel out ? and how will covalent bonds of Na-O or O-H as reactants cancel out ?
Thanks! :)