Solving Chemistry Enthalpy Homework: Step-by-Step Guide

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Discussion Overview

The discussion revolves around a chemistry homework problem involving the calculation of enthalpy change (ΔH) for the reaction of ethane (C2H6) to produce ethylene (C2H4) and hydrogen (H2). Participants explore the correct approach to relate the given enthalpy change to the mass of reactants, focusing on unit conversions and mole calculations.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant states the need to divide ΔH by 2 and multiply by 6g, expressing confusion about the resulting units of kJ*g and the necessity to divide by grams.
  • Another participant suggests determining the weight of a mole of C2H6 to clarify the calculations, noting a discrepancy with the book's value.
  • A third participant asserts that the enthalpy is given for two moles and emphasizes the importance of finding the number of moles in the calculation.
  • One participant presents their calculation leading to an answer of -16.05 kJ, questioning the origin of the number 30g used in their calculations.
  • Another participant challenges the logic of the previous calculation, prompting a focus on the fraction of a mole represented by 6 grams of C2H6.
  • A later reply emphasizes the importance of unit cancellation in the calculations, providing a formula to clarify the conversion process.

Areas of Agreement / Disagreement

Participants express differing views on the correct approach to the problem, particularly regarding the conversion from grams to moles and the appropriate use of enthalpy values. No consensus is reached on the correct calculation method or the origin of the number 30g.

Contextual Notes

Participants note the absence of enthalpy values for individual components and the reliance on provided data. There is uncertainty regarding the correct conversion factors and the interpretation of the enthalpy change given in the problem.

laurenM
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Homework Statement



Given 2C2H6 \rightarrow2C2H4(g) 2H2(G) \Delta H=-64.2kJ

\Delta H for the reaction of 6.000g of C2H6(g) to givev C2H4(g) andH2(g) is

Homework Equations


\Delta H = \Sigma products - \Sigma reactants
q=ct
keeping the units
The enthalpies are not given and are not to be looked up

The Attempt at a Solution


I understand that i have to divide ΔH by 2 and multiply by 6g
but that gives me a unit of kJ*g so i need to divide by grams to get the units right... my solution book tells me to divide by 30g but i am unaware as to where that comes from
 
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You are given the enthalpy for a reaction of one mole. How much does a mole weigh in grams of this material? That would be my thinking, but the book has a slightly different number than I would expect
 
Book is right.

BOYLANATOR said:
You are given the enthalpy for a reaction of one mole.

Enthalpy is given for two moles, not for one. But generally speaking you are on the right track, it is abut finding number of moles.
 
The answer from the book is-6.41 kJ. I found the mols of C2H6 and used the ratio to figure out the sum of mass of reaction and products to get to get 12.00g this gives me the answer of -16.05 kJ.
=-64.2/2 to get it to a 1 to 1 ratio
=-32.1*6 multiply by 6.00g
=-192.6/12
=-16.05 kJ
if you divide by 30 instead of 12 you get the right answer i just don't get where it comes from
 
I don't follow your logic here. You worked out the enthalpy would be -32.1 kJ for a one mole reaction. That's ok.

But in this case it's not one mole of C2H6, it's 6 grams. What fraction of a mole is 6 grams?
 
Just make sure that the units cancel properly:

(32.1 \frac{kJ}{mole})(\frac{1mole}{30grams})(6grams)=? kJ
 

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