Why do we need natural transformations?

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Few days ago, I was thinking about why we need to define V*=Hom(V,K) for a K-vector space when the dimension of V is finite because then V* and V both will have the same dimension and will be isomorphic. So, I couldn't understand why such a thing would be even called a dual vector space if it's the same thing algebraically when the dimension is finite. Then I read that these two vector spaces are isomorphic but there's no natural isomorphism between them.

I'm familiar with some terminology in category theory. I know the definition of a natural transformation in category theory. But I don't understand why natural definitions are important. I remember somewhere I read that Mac Lane has said that he didn't invent category theory to study functors, he invented it to study natural transformations.

Can someone explain to me in layman terms why natural transformations are interesting and how I should think of them?
 
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Maybe it is also interesting to understand what happens , i.e., what are the overall advantages when you do have a natural, basis-independent choice, like when you have a non-degenerate bilinear form associated to your space, like, say, a Riemannian metric ( which gives you the natural "musical isomorphism" between tangent and cotangent spaces). I guess in the case of R^n, life becomes simpler in terms of differentiating ( trivial Euclidean connection) , but I can't think now of other areas where having a natural , canonical isomorphism helps, or at least what are other implications of having a natural isomorphism.
 
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##\textbf{Exercise 10}:## I came across the following solution online: Questions: 1. When the author states in "that ring (not sure if he is referring to ##R## or ##R/\mathfrak{p}##, but I am guessing the later) ##x_n x_{n+1}=0## for all odd $n$ and ##x_{n+1}## is invertible, so that ##x_n=0##" 2. How does ##x_nx_{n+1}=0## implies that ##x_{n+1}## is invertible and ##x_n=0##. I mean if the quotient ring ##R/\mathfrak{p}## is an integral domain, and ##x_{n+1}## is invertible then...
The following are taken from the two sources, 1) from this online page and the book An Introduction to Module Theory by: Ibrahim Assem, Flavio U. Coelho. In the Abelian Categories chapter in the module theory text on page 157, right after presenting IV.2.21 Definition, the authors states "Image and coimage may or may not exist, but if they do, then they are unique up to isomorphism (because so are kernels and cokernels). Also in the reference url page above, the authors present two...

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