An object appears darker when wet primarily due to changes in light reflection and refraction. When dry, a rough surface scatters light in various directions, while a wet surface becomes smoother, reflecting light more directly, similar to a mirror. This smoothness reduces the amount of light scattered back to the observer, contributing to the darker appearance. Additionally, the interaction between water and the object's molecules can alter absorption frequencies, allowing more wavelengths to be absorbed, further darkening the object's appearance. Overall, the combination of surface smoothness and molecular interaction with water explains why wet objects appear darker.