Why is a Hexagonal Prism Used as the Unit Cell for 3D HCP?

In summary, textbooks state that all 14 bravais lattices have one of the 7 types of parallelepiped that can be used as a unit cell. However, in the case of 3D HCP, textbooks use a hexagonal prism as the unit cell instead of a parallelepiped. This is because the hexagonal prism is a combination of the hexagonal and rhombohedral crystal systems, providing the necessary symmetry for the atoms to form a lattice structure. The rhombohedral system is formed by a cube with its edges cut at an angle, and the hexagonal system adds an additional angle to create the hexagonal prism shape.
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My textbook states that all the 14 bravais lattices have one of the 7 types of parallelepiped (7 crystal systems) that can be used as an unit cell. However in case of 3D HCP textbooks don't talk about this parallelepiped, rather they consider a hexagonal prism as the unit cell. Why is it so? Also is this hexagonal prism a combination of rhombohedral and hexagonal crystal system?
 
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The hexagonal prism is the unit cell of the HCP Bravais lattice, and it is a combination of the hexagonal and rhombohedral crystal systems. The hexagonal prism has three perpendicular axes of symmetry (one of length a, one of length b, and one of length c) and two non-perpendicular angles (gamma and alpha). This shape allows the atoms to organize into a lattice structure with a hexagonal base and a prism-like top. The rhombohedral system is formed by a cube with its edges cut at an angle, allowing for threefold symmetry in all three dimensions. In the case of HCP, the rhombohedral system is the cube with its edges cut at the gamma angle. The hexagonal system adds the alpha angle, which is necessary to form the hexagonal prism shape.
 

1. Why is a hexagonal prism used as the unit cell for 3D HCP?

The hexagonal prism is used as the unit cell for 3D HCP because it is the simplest shape that can fully describe the repeating pattern of atoms in a hexagonal close-packed (HCP) crystal structure. This shape allows for efficient packing of atoms, resulting in a stable and strong crystal lattice.

2. What is the significance of the hexagonal prism in 3D HCP?

The hexagonal prism is significant in 3D HCP because it represents the basic building block of the crystal structure. All other unit cells in the crystal lattice can be derived from this shape through translations and rotations.

3. How does the hexagonal prism unit cell relate to the structure of HCP crystals?

The hexagonal prism unit cell is a representation of the close-packed layers of atoms in an HCP crystal. These layers are arranged in a hexagonal pattern, with each layer slightly offset from the one below it. This arrangement creates a strong and stable crystal structure.

4. Can other shapes be used as the unit cell for 3D HCP?

While the hexagonal prism is the most commonly used unit cell for 3D HCP, other shapes can also be used. However, these shapes must still be able to fully describe the repeating pattern of atoms in the crystal structure and maintain the efficient packing of atoms.

5. How does the hexagonal prism unit cell affect the properties of HCP materials?

The hexagonal prism unit cell plays a crucial role in determining the properties of HCP materials. Its shape and arrangement of atoms contribute to the crystal's strength, ductility, and other physical and chemical properties. Changes in the unit cell can greatly impact the overall properties of the material.

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