Colloid complex refractive index from UV-vis spec

  • Level: Undergrad 
  • Thread starter CheesyG
  • Start date
  • Tags Tags
    Refractive index
1 reply · 3K views · last reply
CheesyG
Messages
4
Reaction score
0
TL;DR
Can I determine the complex refractive index (n + ik) of a colloid via UV-vis spectroscopy?
Hi everyone,

I am wondering, can I use the damped wave approximation for light travelling through a medium along with Beers law to spectroscopically determine a colloid complex refractive index.
Thanks!

Absorbance = exp (- 2πkx/λ) = ecl
 
I think it's possible. You could extract k as a function of wavelength, and then fit a series of Lorentz oscillators to it. This would then give you n. Beware though, if you don't understand the physics of your material, then I'd say that you could end up with numbers that aren't a good match to reality.
 
  • Like
Likes   Reactions: Lord Jestocost