Why won't C4 explode when heated but a shockwave can set it off?

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C4 does not explode when heated because it undergoes a different reaction mechanism that causes it to burn slowly instead of detonating. This behavior is due to the stability of its chemical structure under heat, which contrasts with the rapid energy release triggered by a shockwave. The discussion highlights that different reactions can occur under varying conditions, similar to how certain polymer reactions behave. An analogy is drawn with egg whites, where applying heat alone does not create meringue, but mechanical action (beating) breaks bonds to achieve a different result. This illustrates the principle that the method of energy application significantly influences the reaction outcome.
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I asked my chem teacher but they had no answer so maybe you guys know. Why is it that C4 won't explode when heated (why does it burn slowly?) but a shockwave will set it off?
 
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Serj said:
I asked my chem teacher but they had no answer so maybe you guys know. Why is it that C4 won't explode when heated (why does it burn slowly?) but a shockwave will set it off?

Simply put there are 2 different reaction mechanisms. This is not all that uncommon. In some polymer reactions

nA + Δ -> An while if severely stirred nA -> garbage.

The second example is a mechanical process of braking bonds. An common household example of this is egg whites. No matter how much heat you apply to an egg while you will never end up with a meringue. When you beat the egg whites you are actually braking bonds (yes you are also aerating it).
 
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