Will All Metals Deposit on the Copper Cathode in My Electrolysis Experiment?

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In a backyard experiment involving a leach solution of 1 part sulfuric acid to 4 parts tap water, the discussion centers on the electrolysis process using a lead anode and a copper cathode. The primary focus is on the deposition of metals such as copper, iron, and cobalt from the solution. It is clarified that while copper is likely to deposit on the cathode, the presence of hydrogen in the solution will hinder the deposition of other metals. The reactivity series is mentioned as a useful tool for understanding which metals might deposit, indicating that copper is the primary metal expected to deposit in this setup, with the possibility of silver depositing if present. The conversation highlights the importance of electrorefining in the purification of copper.
Ash1111
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Hi. I am a complete novice working on my first backyard experiment.

I have a 1part sulphuric acid 4parts tap water pregnant leach solution (from old copper mine tailings).

If I were to set up an electrolysis type experiment with a lead anode and a copper cathode should I expect all the metals (i.e. copper, iron, cobalt) in the solution to be deposited onto the cathode?

Thanks
 
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I don't think so. Copper, yes, but you have plenty of hydrogen to reduce before seeing these metals depositing.

Do you know what reactivity series is? While it is only approximate in many ways, it should give you a starting point.
 
Thanks Borek. Much appreciated!

Do you mean that copper is the only metal that might deposit in that experimental set up if the hydrogen count was right?
 
Ash1111 said:
Do you mean that copper is the only metal that might deposit in that experimental set up

Yes, that's why we use electrorefining for copper purification.

Note that some other metals (like silver) will deposit on the electrode as well (assuming it is present in the solution). It depends on where they are on the reactivity scale.
 
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