In FCC cubic structures, there are 12 slip systems consisting of 4 unique {111} planes and 3 <110> directions. The 4 unique {111} planes arise because, although 8 {111} planes can be drawn, only 4 are distinct due to parallelism and spacing. The confusion regarding the <110> directions stems from the cube's rotational symmetry, which allows for the transformation of face diagonals into one another, reducing the count to 3 unique directions. This symmetry means that while there appear to be 6 face diagonals, they can be derived from just one relevant <110> direction. Understanding these concepts is crucial for grasping the fundamentals of crystallography in materials science.