How do you calculate activation energy per vacancy?

AI Thread Summary
To calculate the activation energy needed to create a single vacancy in aluminum at 500 Celsius, the relevant formulas involve the density, number of vacancies, and Boltzmann's constant. The initial calculation yielded an activation energy of 1.053 eV/atom, which was significantly lower than the expected 72.33 kJ/mol. It was clarified that the discrepancy arose from not converting the energy per atom to energy per mole correctly. The correct approach involves multiplying the energy per atom by Avogadro's number to obtain the value per mole. This discussion highlights the importance of unit conversions in thermodynamic calculations.
ENgez
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the question is like this:
Calculate the activation energy needed to create a single vacancy in aluminium, given:
T= 500 Celsius
Density (500 Celsius) = 2.62 gr/cm3
n = 7.57e23 m-3
Mw (Al) = 26.98 gr/mol

I know these Formulas:
n = N*exp (Q/kT) (k = boltzmann's constant)
N = Na*Density/Mw (Na = avogardo's number)
 
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Hey ENgez, welcome to PF :smile:

It seems like a direct question with a direct answer, just find Q [the activation energy required to create one vacancy].
 
I did Find Q and it turned out to be 1.053 ev/mole or 16.85e-20 Joule/mole, but according to the answer sheet its supposed to be 72.33 kJoule/mole. Is it possible for the answer to be so big or is there a mistake in the sheet? And if there isn't, what am i doing wrong?

Btw, thanks drizzle :)
 
An energy value like 1.053 ev, should be on the basis of an atom.
 
Did you convert Celsius to kelvin?
 
I solved it :). Thank you Astronuc and drizzle. Astronuc, your post made me see that i had actually found the energy per atom, so all i had to do was to multiply it by avagardo's number to get it per mole.
 
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