Limewater Test: Dedicated Test for Carbon Dioxide

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The discussion centers on the limewater test, which is commonly used to detect carbon dioxide. Both carbon dioxide and sulphur dioxide can turn limewater milky, leading to confusion about the specificity of the test. While it is noted that prolonged exposure to sulphur dioxide can eventually lead to a clear solution due to the formation of calcium sulfide, this does not make it a reliable test for sulphur dioxide. Additionally, an excess of carbon dioxide can also result in a clear solution through the formation of calcium hydrogencarbonate, complicating the interpretation of results. The conversation highlights the misconception that the limewater test is exclusively indicative of carbon dioxide, as both gases can yield similar outcomes under certain conditions. However, there is a correction regarding the formation of calcium bicarbonate, asserting that it does not occur as a solid.
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Carbon dioxide and sulphur dioxide both can turn limewater milky. Either the presence of carbon dioxide and sulphur dioxide can give a positive test result. Why limewater test can be a dedicated test for carbon dioxide?
 
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abcd8989 said:
Why limewater test can be a dedicated test for carbon dioxide?

It isn't. (But if you pass SO2 through it long enough, it will form CaS and become clear again, so in this particular case, it can be a test if you have enough gas.)
 
alxm said:
It isn't. (But if you pass SO2 through it long enough, it will form CaS and become clear again, so in this particular case, it can be a test if you have enough gas.)
If excess amount of carbon dioxide is bubbled into limewater, a clear solution can also be formed (calcium hydrogencarbonate formed). So, excess gas also cannot distinguish between sulphur dioxide and carbon dioxide. I wonder why we usually conclude that carbon dioxide is present if a positive result is shown in limewater test, ignore that it is the presence of sulphur dioxide leading to the positive result.
 
abcd8989 said:
If excess amount of carbon dioxide is bubbled into limewater, a clear solution can also be formed (calcium hydrogencarbonate formed).

Not true. You will never make a bicarbonate of calcium. It just doesn't happen. ... as a solid anyway.
 
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