sophiecentaur said:
You don't need a chemical reaction between glycerol and water or between mercury and copper to change the melting point considerably.
You say that you are speaking as a Physicist (and so am I) but I, certainly, have little knowledge of the behaviour of substances at extreme pressure. Do you?
If you look at the phase diagram of water, it remains solid at very high temperatures when the pressure is high enough. I think we need to look in much more detail if we want to be able to hold a valid opinion about this. Personally, I'm open to any good information that turns up on this thread.
By the word "Science" I mean to say not just physical or chemical or geological but any. That's why I mentioned that I am not a geologist and my common sense speaks what I mentioned.
I think there doesn't need any knowledge other than those few Gaseous laws of Robert Boyle and Charles. So, I proposed my 'common sense' based on this.
Water can never stay in solid form inside the deep layers of earth. Either it should be in the form of colloids (liquid form) or gaseous form. I don't have a confirmation whether the water is in gaseous form under the Earth. (If so, then there should be sesmic vibrations experienced all around the Earth, not just at the places where techtonic plates collide).
How much ever water tries to form a colloid its polarization (because its a non-polar solvent) can't cross more than 180 degrees. Anything more than 120 degrees of polarization is quite impossible without electric supply. Water needs to form heavy polarization with is fellow colloid in order to sustain such heavy temperatures. In that case water molecule simply breaks down rather than staying there completely polarized.
There are two cases where water may form colloids. 1) solid in Liquid 2) liquid in liquid.
If solid in liquid is the case, then water definitely stays away from the solid it is mixed with, since their densities vary by heavy amount which makes them impossible to mix, unless they react chemically. Its a kind of Adsorption phenomena. Even if they mix, water can't account for greater than 2-3% of the colloid just soaking it wet. Given the area taken into consideration (as radius sinks and so is surface area as we go deep), we find very little water in the deeper layers of the earth.
If liquid in liquid is the case. Liquid can mix with liquid only in case as mentioned above (polarization). If there is some material in the form of liquid at that particular (heavy) temperature and pressure, then it must have heavier energy due to brownian motion. We know, when such high energy molecules collide with water molecules of lower energy, they, obviously, are ejected out. This is the practical case.
I state again, I am not a geologist, nor a chemist, nor a physicist. I stated something out of common sense and my high school chemical sciences. There may be other factors taken into consideration which I am not aware of. If anyone cares to mention them, I'll be glad to know about.