Does iron react into gas phase?

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At high temperatures around 1400 K in a hydrogen atmosphere, iron contamination on silicon is a concern, particularly regarding its phase behavior. Both iron and silicon exhibit measurable vapor pressures at elevated temperatures, but significant vaporization of iron is not expected. The discussion highlights that while ferrosilicon formation may occur, it is unlikely to vaporize in substantial amounts. The primary focus is on determining the retention of iron within silicon during high-temperature silicon epitaxy chemical vapor deposition processes. The consensus suggests that most iron will remain within the silicon matrix and diffuse throughout rather than transitioning to the gas phase, prompting the need for analytical methods to verify these assumptions.
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I'm looking at iron contamination on silicon and I'm wondering if, at high temperature (1400 K), and in a hydrogen atmosphere, should I expect some iron to change to gas phase?
 
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Both iron and silicon have measurable vapor pressures at elevated temperatures. I wouldn't expect iron or silicon to appreciably react with hydrogen, if that's your question.
 
My goal is to figure out how much iron will remain in the silicon and how much will transfer to gas phase in a high temperature silicon epitaxy chemical vapor deposition reaction.

I know there will be some degree of ferrosilicon formation. Do you think these might vaporize in significant amounts?

I'm thinking the large majority of the iron will remain in and diffuse throughout the silicon, but I'm trying to find a way to verify this analytically.
 
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