Why is the diffusion coefficient in Fick's law squared?

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Fick's first law of diffusion describes the relationship between diffusion flux and concentration gradient, where the diffusion coefficient (D) is crucial. The confusion arises from the units of D, which are area/time, indicating that it measures the flux of material passing through a surface area over time. This area component is necessary because diffusion occurs across a surface, not just along a line. The squared length in the diffusion coefficient accounts for the dimensionality of the diffusion process, ensuring that the equation remains consistent in terms of units. Understanding these concepts clarifies why area is integral to the diffusion equation.
jjmclell
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Hi there,

I'm trying to wrap my head around Fick's first law of diffusion (for one dimension):

J_{x} = -D \frac{\partial \phi}{\partial x}

I understand that \phi is the concentration in units amount/volume and that x is position on the gradient in units length. What I don't understand is why -D is in units area/time. If we're talking one dimensional diffusion, why do we bring area into the equation? Or, put another way, why do we square length in the diffusion coefficient?

Thanks,

jjmclell
 
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It's in units of area/time because it represents the flux of material through a (control) surface
 
So I know that electrons are fundamental, there's no 'material' that makes them up, it's like talking about a colour itself rather than a car or a flower. Now protons and neutrons and quarks and whatever other stuff is there fundamentally, I want someone to kind of teach me these, I have a lot of questions that books might not give the answer in the way I understand. Thanks
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