Alcohol gel cooled with dry ice

AI Thread Summary
When cooling 91% isopropyl alcohol with dry ice, it transformed into a thick gel, prompting questions about the underlying chemistry. The gel formation may be attributed to the presence of 9% water in the solution, which could influence the intermolecular forces at low temperatures. The discussion highlights the role of hydrogen bonds in the alcohol, suggesting they contribute to both gelling and solidifying behaviors. Observations noted include a minimal increase in volume upon returning to room temperature, complicated by CO2 gas bubbles. The lack of a Tyndall effect suggests that the gel does not behave like a colloid, and its viscosity was insufficient to maintain shape in an inverted cup. The temperature of the gel was challenging to measure accurately, as it fell below the range of standard thermometers.
mishima
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Hi I tried cooling down some 91% isopropyl alcohol with dry ice. After a few minutes, the alcohol became a thick gel. I am wondering what is going on there, thanks.
 
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I mean why does it become gel? I tried putting some in a graduated cylinder and only noticed a slight (1mL) increase in volume after it returned to room temperature. However it also contained a great deal of CO2 gas bubbles making the cold reading difficult.
 
Perhaps 9% of water is what makes it gelling instead of nicely solidifying.
 
I'm not sure, dry ice gets a shell/coating of water ice when submerged in water. Could it extract the 9% from solution? I wasn't specifically looking for such a shell so I don't know if that happens/is possible. I was thinking intermolecular forces might be coming into play at the low temperature.
 
No doubt about intermolecular forces playing their part - but they are responsible both for gelling and for solidifying (actually they are also responsible for keeping liquid in place).
 
Do you think its the hydrogen bonds coming off the alcohol group, specifically?

I actually don't know the technical definition of a gel, I thought it was like a colloid but I did not see the Tyndall effect. I don't think it was quite viscous enough to stay put in an inverted cup, it bubbled violently and evaporated rapidly when poured on a room temperature surface. It was below range of both my non-contact thermometer and my normal alcohol thermometer, but I assume close to the temperature of dry ice.
 
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