Adding angular momentum of 2 electrons

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SUMMARY

The discussion focuses on calculating the possible values of total angular momentum (s', l', j') for two electrons with orbital angular momenta l1=1 and l2=3, and spins s1=1/2 and s2=1/2. The total spin S' can yield eigenvalues of s'=0 and s'=1, while the total orbital angular momentum L' can range from l'=2 to l'=4. The total angular momentum J' is derived from J'=L'+S', leading to j' values of l'+1/2 and l'-1/2. The confusion arises regarding the additional six states, which necessitates consideration of the magnetic quantum numbers m_l.

PREREQUISITES
  • Understanding of angular momentum addition rules in quantum mechanics
  • Familiarity with quantum numbers, specifically spin and orbital angular momentum
  • Knowledge of the eigenvalues of angular momentum operators
  • Basic grasp of the concept of magnetic quantum numbers (m_l)
NEXT STEPS
  • Study the addition of angular momentum in quantum mechanics using textbooks like "Quantum Mechanics: Concepts and Applications"
  • Research the significance of magnetic quantum numbers (m_l) in determining the states of a quantum system
  • Explore the implications of total angular momentum in multi-electron systems
  • Learn about the Clebsch-Gordan coefficients for combining angular momentum states
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Students and educators in quantum mechanics, physicists working with angular momentum in atomic systems, and anyone studying the behavior of multi-electron atoms.

Andrusko
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Homework Statement



Use the rules for addition of angular momentum vectors to show that there are 12 possible values of (s',l',j') for two electrons with l1=1, l2=3, s1=1/2, s2=1/2.

Homework Equations



Total Spin S'=S1 + S2
Total orbital angular momentum L'=L1 + L2

Total angular momentum of system J'=L'+S'

The Attempt at a Solution



the spin vector S' can have eigenvalues s'=0,1 (I don't know why it just written in the textbook)

the L' vector apparentely has the rule that l' = abs(l1-l2) ... l1+l2

so that gives l' = 2, 3, 4

and apparentely j'= l'+1/2,l'-1/2

So two j' for each l' means a total of 6 states. Where's the other 6?

My only thought is that you have to somehow take m_{l} quantum numbers into account but I'm totally confused about that because I don't understand anything about m_{l} quantum numbers.
 
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Andrusko said:

Homework Statement



Use the rules for addition of angular momentum vectors to show that there are 12 possible values of (s',l',j') for two electrons with l1=1, l2=3, s1=1/2, s2=1/2.

Homework Equations



Total Spin S'=S1 + S2
Total orbital angular momentum L'=L1 + L2

Total angular momentum of system J'=L'+S'

The Attempt at a Solution



the spin vector S' can have eigenvalues s'=0,1 (I don't know why it just written in the textbook)

the L' vector apparentely has the rule that l' = abs(l1-l2) ... l1+l2
The same rule applies for s', so s' ranges from |1/2-1/2|=0 to 1/2+1/2=1.
so that gives l' = 2, 3, 4

and apparentely j'= l'+1/2,l'-1/2
You want to use the values for s', which as you noted above are 0 and 1, not 1/2.
So two j' for each l' means a total of 6 states. Where's the other 6?

My only thought is that you have to somehow take m_{l} quantum numbers into account but I'm totally confused about that because I don't understand anything about m_{l} quantum numbers.
 

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