The Transfer in Quanta of Radiation Momentum to Matter
1. The reflection by a crystal of X-radiation characteristic of the atoms in the crystal itself, which Dr. G. L. Clark and the writer discovered, does not appear to be explainable in a simple manner by the theory of interference of waves. This note describes an attempt to formulate a theory of the reflection of X-rays by crystals, based on quantum ideas without reference to interference laws.
2. The fundamental hypothesis of the theory now presented is that
the momentum of radiation is transferred to and from matter in quanta, and further, that the laws of the conservation of energy and of momentum apply to these transfers.
3.In order to illustrate the meaning of this hypothesis, let us take a particular example, namely, that of the reflection of an X-ray by a crystal.
...
This is Braggs' law of reflection of an X-ray by a crystal.
By similar reasoning, if
τ' = 0 and
τ differs from 0, we deduce the equation:
τλ' = 2a cos θ,
which represents reflection according to
Braggs' law from the
y-planes. If both τ and τ' differ from 0, the equation obtained reduces to Braggs' equation representing the reflection from a set of planes other than the principal planes. In the case where the axes of the crystal are not at right angles to each other, we apply the law of the transfer of momenta in quanta to the total component of the radiation momentum in the direction of each axis and we equate this component to
τh/a where
a is the parameter of the crystal along the axis. This gives us equations which reduce to Braggs' equation for the reflection from each set of planes, as in the orthogonal problem.