Boiling point and vapor pressure

In summary, boiling occurs when the vapor pressure of a liquid reaches the surrounding atmospheric pressure, allowing the liquid to spontaneously turn into steam. This happens because the pressure around the liquid is lower than the pressure at which the steam wants to form, causing the molecules to break away and absorb latent heat.
  • #1
sashankhrao
19
0
I am trying to understand the concept of boiling from a very fundamental perspective. Most textbooks say that: as a liquid is heated, it's vapor pressure increases. When the vapor pressure reaches the surrounding pressure(or atmospheric pressure at that point), then boiling occurs.

I agree with the above point.

My question is: when the vapor pressure reaches the surrounding pressure, what physically happens that allows vapor to form all through the liquid for it to boil.

Thanks
 
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  • #2
Pressure is what prevents a volume of water from spontaneously flashing into steam - be it air pressure above or water pressure around it. If a volume of water gets hot enough that it "wants" to be steam at a certain pressure and the pressure around it is lower than that, it will spontaneously flash to steam.
 
  • #3
Thank you for your reply.

So if the vapor pressure reaches the surrounding atmospheric pressure, how does that lead to the pressure around the volume of water being lower than the pressure with which the steam wants to form?

By "wants", do you mean that the molecules break away from surrounding molecules by absorbing the latent heat?
 

1. What is the boiling point of a substance?

The boiling point of a substance is the temperature at which its vapor pressure is equal to the atmospheric pressure, causing it to change from a liquid to a gas.

2. How is boiling point affected by changes in atmospheric pressure?

As atmospheric pressure increases, the boiling point of a substance also increases. Conversely, as atmospheric pressure decreases, the boiling point decreases as well.

3. How does the strength of intermolecular forces affect boiling point?

The stronger the intermolecular forces between molecules, the higher the boiling point of a substance will be. This is because more energy is required to overcome these forces and allow the substance to change from a liquid to a gas.

4. Can boiling point be used to identify a substance?

Yes, the boiling point of a substance is a physical property that can be used to identify it. Each substance has a unique boiling point, so by measuring the boiling point, one can determine the identity of the substance.

5. How does vapor pressure relate to boiling point?

Vapor pressure is the pressure exerted by a substance's vapor in equilibrium with its liquid phase. At the boiling point, the vapor pressure of a substance is equal to the atmospheric pressure. As the temperature increases, so does the vapor pressure, eventually reaching the atmospheric pressure and causing the substance to boil.

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