Calculate the mass of nitrogen dissolved

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To calculate the mass of nitrogen dissolved in a 92.0 L aquarium at 1.0 atm with a mole fraction of 0.78, the ideal gas law (PV=nRT) was initially applied, yielding a result of 82.18 g. However, this calculation represents the mass of nitrogen gas, not the mass dissolved in water. The correct approach involves using Henry's Law, which requires the Henry's Law constant for nitrogen to determine the actual mass dissolved. The discussion highlights that for homework assignments, specific constants may need to be looked up, while exams will provide necessary values. Ultimately, understanding the distinction between gas mass and dissolved mass is crucial for accurate calculations.
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Homework Statement



Calculate the mass of nitrogen dissolved at room temperature in a 92.0 L home aquarium. Assume a total pressure of 1.0 atm and a mole fraction for nitrogen of 0.78.

Homework Equations



PV=nRT

The Attempt at a Solution



P_{total}=1 atm

P_{N}=.78 atm

V=92LSo here is what I did:
n=\frac{PV}{RT} = \frac{(.78)(92)}{(.08206)(298.15)}

n=2.93303

mass = (2.93303 mol)\frac{28.02g}{mol}

mass = 82.1834g

This is an online homework assignment and it keeps rejecting my answer. It only wants two sig figs. Any ideas where I am going wrong? Thanks in advance.

Joe
 
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You can't solve this unless Henry's Law constant or Proportionality Constant (in Henry's Law) for Nitrogen is given
 
The mass you calculated is not the mass DISSOLVED.
Instead it is the mass of Nitrogen gas that would be present in a container (evacuated) of 92L at a pressure of 0.78 atm
 
Thanks guys, the Henry's law relationship worked out. This was an online HW so we were allowed to look certain constants up. For the exam he will provide the necessary constants.

Joe
 
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