To calculate gas volume from mass, first determine the moles of the gas, then multiply by 22.4L, which is the volume of one mole at Standard Temperature and Pressure (STP). It's important to note that STP can vary based on the definition used, and the ideal gas equation (pV=nRT) provides a more accurate method. While using 22.4L is a common shortcut, it can lead to inaccuracies if conditions deviate from STP. Understanding the ideal gas law is beneficial for deeper chemistry studies, but for basic calculations, multiplying by 22.4L is often sufficient. Mastering these concepts is essential for anyone pursuing a career in chemistry.