Calculating Mole Fraction of C6H6(l) in Solution

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To find the mole fraction of C_6H_6(l) in the solution, use the formula P_tot = (X_A)(P^o_A) + (1-X_A)(P^o_B). Given the total vapor pressure of 0.485 atm, the vapor pressures of pure components are P^o_C6H6 = 0.526 atm and P^o_C7H8 = 0.188 atm. Substitute these values into the equation and solve for X_A, the mole fraction of C_6H_6(l). The calculated mole fraction should yield approximately 0.879. This method effectively applies Raoult's Law for the solution.
mikep
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does anyone know how to do this problem?
The total vapor pressure above a solution of C_6H_6(l) and C_7H_8(l) is 0.485 atm. What is the mole fraction of C_6H_6(l) in the liquid solution?
P^o C6H6(l) = 0.526 atm
P^o C7H8(l) = 0.188 atm

the answer is 0.879 but I'm not sure how to get that using the formula P_A = (X_A)(P^o _A)
 
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mikep said:
does anyone know how to do this problem?
The total vapor pressure above a solution of C_6H_6(l) and C_7H_8(l) is 0.485 atm. What is the mole fraction of C_6H_6(l) in the liquid solution?
P^o C6H6(l) = 0.526 atm
P^o C7H8(l) = 0.188 atm

the answer is 0.879 but I'm not sure how to get that using the formula P_A = (X_A)(P^o _A)

It's a direct substitution problem.

P_{tot} = P_A + P_B = (X_A)(P^o _A) + (X_B)(P^o _B) = (X_A)(P^o _A) + (1-X_A)(P^o _B)

Now just plug in the given numbers and solve for X_A
 
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