Calculating Reversible Work and Irreversibility in a Filling Container

AI Thread Summary
The discussion revolves around calculating reversible work and irreversibility in a scenario where a rigid, evacuated container fills with atmospheric air after a valve opens. The first law of thermodynamics is applied, with the equation Q + minhin = m2u2, and the heat transfer is expressed as Qout = P0.V. The entropy generation is calculated as Sgen = Q/T = P0.V/T0, leading to the conclusion that irreversibility (I) equals the product of pressure and volume. The participants clarify that reversible work is a theoretical maximum, while irreversible work represents the lost energy in the process. The key challenge is determining the reversible work, which is distinct from the irreversible work that has been identified as zero.
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Homework Statement


A rigid and evacuated container of volume V that is surrounded by atmosphere (P0, T0). At some point neck valve opens and atmospheric air gradually fills the container. The wall of container is thin enough so that eventually the trapped air and atm reach thermal equilibrium. The neck valve remains open, therefore at the end the trapped air and atmosphere are also in mechanical equilibrium. Calculate the reversible work and irreversibility.

Homework Equations

The Attempt at a Solution


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From the first law Q + minhin = m2u2

Qout = P0.V

Sgen=Q/T=P0.V/T0

I = T0S = P0.V = I

I = Wrev - Wirrev

How can I find reversible work? I assumed work is zero in first law. But which work was that irreversible or reversible I don't know.
 
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The irreversible work is the shaft work, which you correctly determined to be zero. The reversible work is a theoretical quantity, representing the work that could have been done. The irreversibility is the lost work.
 
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