Can Adding Water to Molten Salt Increase the Boiling Point of Salt or Water?

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Adding impurities like salt to water raises its boiling point, but the reverse scenario of adding water to molten salt raises questions about boiling point changes. Water is not typically considered an impurity in molten salt, but introducing it can lead to significant steam production due to the temperature difference between water and ionic melts, which range from 500 to 1500 degrees Celsius. Conducting experiments to measure melting point depression in ionic melts with water as an impurity would necessitate high pressure to maintain phase stability, as melting points are colligative properties. However, the dynamics of boiling points become complex since water cannot remain liquid above its critical point. This phenomenon mirrors geological processes in subduction zones, where moisture-rich minerals melt beneath tectonic plates, leading to the formation of magma. As this magma ascends, it can depressurize and potentially erupt explosively, releasing water vapor.
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If adding impurities, such as salt, to water will increase the boiling point of water, what if it's the other way around? Will adding water to molten salt increase the boiling point of salt (sodium chloride) or the water? Or water is not considered an impurities to molten salt?
 
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As you might guess, adding liquid water which has STP boiling point of 100C is a good way to get a lot of steam from contact with typical ionic melts which are in the 500-1500 C range. The experiment to determine mp depression for ionic melts with H2O as an impurity would require high pressure to keep the phases mingled. But since mp's are colligative properties, the same principles apply. For ionic melts transitioning to boiling points things become more complicated as H2O even under pressure can not be a liquid (above critical point).

However, this is exactly what is taking place deep beneath the Earth in subduction zones that take an oceanic plate and slide it under a continental plate. A moisture rich mineral phase begins to melt at some point below the lowest melting mineral, and the less dense hot fluidic magma rises through denser rock. As it nears the surface the hot vapor rich magma can depressurize and further fractionate depending on the cooling rate of the surroundings. If it rises to the surface it can release the water explosively in a volcanic eruption.
 
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