Temperature can affect the volume of air in a room, and the ideal gas law (PV=NRT) is relevant for understanding this relationship, specifically when using absolute temperature in Kelvin. The discussion revolves around determining the temperature required to expand air volume by a factor of 1.05, with some confusion about whether to redefine the problem in terms of volume change or the number of molecules. Clarifications emphasize that while volume and the number of molecules are proportional under constant conditions, temperature is variable in this scenario. The conversation highlights the importance of maintaining clarity in homework discussions and the need for careful consideration of the problem's parameters. Understanding these relationships is crucial for accurately applying the ideal gas law.