Canonical ensemble, entropy of a classical gas

hansbahia
Messages
54
Reaction score
0

Homework Statement



I have the equation
Z=1/N!h3N∫∫d3qid3pie-βH(q,p)

How can I get the entropy from this equation assuming a classical gas of N identical, noninteracting atoms inside a volume V in equilibrium at T where it has an internal degree of freedom with energies 0 and ε
What about the specific heat at constant volume Cv?
Can anyone explain the equation?

Homework Equations



Z=1/N!h3N∫∫d3qid3pie-βH(q,p)

The Attempt at a Solution



Well I integrated the momentum and the volume separately. At the end I did get PV=NRT where I'm supposed to show that from this equation I can derive to the ideal gas law equation
∫d3q=VN=Vn/N!
∫d3p=0

However by using Z equation I can derive the entropy for this problem, how?
what about specific heat?
 
Physics news on Phys.org
Lets say the partition function is Z = Ʃ e-βH where the sum runs over all possible configurations (it's a path integral or whatever). Then the probability of a single state is P = e-βH / Z. The entropy is defined as usual, S = -kB Ʃ P ln P where sum is again over all states. Using this knowledge, you should be able to show that S = -β2 ∂/∂β (1/β ln Z).

As for the actual calculation, remember that the Hamiltonian of classical gas molecules is Hi = pi2/2m. Also take into account the extra degree of freedom by adding an extra factor into the Hamiltonian (and sum over all possibilities again). Finally, remember that since your particles are not interacting, the partition function should simplify into a direct product of N single particle systems
Z_1 = \int d^3p d^3q \sum_{\epsilon} \exp(-\beta H_1(p,q,\epsilon))
Z_N = \frac{1}{N!} Z_1^N
 
Thread 'Need help understanding this figure on energy levels'
This figure is from "Introduction to Quantum Mechanics" by Griffiths (3rd edition). It is available to download. It is from page 142. I am hoping the usual people on this site will give me a hand understanding what is going on in the figure. After the equation (4.50) it says "It is customary to introduce the principal quantum number, ##n##, which simply orders the allowed energies, starting with 1 for the ground state. (see the figure)" I still don't understand the figure :( Here is...
Thread 'Understanding how to "tack on" the time wiggle factor'
The last problem I posted on QM made it into advanced homework help, that is why I am putting it here. I am sorry for any hassle imposed on the moderators by myself. Part (a) is quite easy. We get $$\sigma_1 = 2\lambda, \mathbf{v}_1 = \begin{pmatrix} 0 \\ 0 \\ 1 \end{pmatrix} \sigma_2 = \lambda, \mathbf{v}_2 = \begin{pmatrix} 1/\sqrt{2} \\ 1/\sqrt{2} \\ 0 \end{pmatrix} \sigma_3 = -\lambda, \mathbf{v}_3 = \begin{pmatrix} 1/\sqrt{2} \\ -1/\sqrt{2} \\ 0 \end{pmatrix} $$ There are two ways...
Back
Top