Compressibility of liquid vs solid actual numbers

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Discussion Overview

The discussion revolves around the compressibility of liquids, specifically water, in comparison to gases, particularly hydrogen. Participants explore the definitions and calculations related to compressibility, the relationship between compressibility and viscosity, and how pressure affects these properties.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • Some participants note the compressibility of water as 46.4e-6, while expressing difficulty in finding compressibility values for gases.
  • There is a discussion about the compressibility factor for gases, with some suggesting that for ideal gases, it is equal to 1.
  • Participants question the relationship between viscosity and compressibility, with some expressing skepticism about any direct link.
  • One participant clarifies that the value for liquid water likely refers to the reciprocal of the bulk modulus rather than the compressibility factor.
  • Another participant presents a formula for compressibility from a textbook and discusses its derivation.
  • A participant attempts to compare the compressibility of water to that of an ideal gas, suggesting that water is significantly less compressible, but others challenge this by emphasizing the importance of pressure in such comparisons.
  • There is a clarification that the compressibility of liquid water is relatively insensitive to pressure, while that of an ideal gas is sensitive to pressure changes.
  • Some participants seek to confirm whether the compressibility values discussed are based on standard atmospheric pressure.

Areas of Agreement / Disagreement

Participants express differing views on the relationship between compressibility and viscosity, and there is no consensus on the comparison of compressibility between water and ideal gases without specifying pressure conditions. The discussion remains unresolved regarding the implications of viscosity on compressibility.

Contextual Notes

Participants reference specific values and sources for compressibility, but there are uncertainties regarding the definitions and units used in the calculations. The discussion highlights the need for clarity on pressure conditions when making comparisons.

fahraynk
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I was trying to find the compressibility of water and compressibility of air to compare.
For compressibility of water I found 46.4e-6
For compressibility of a gas... I am having a tough time finding anything. compressibility factor I can find, which is 1 for Hydrogen... but how does that relate to compressibility?

Also... if a liquid is much more viscous than water... water is .001[Pa*sec] so say if the viscosity = 2 then would it likely be more or less compressible than water?
 
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fahraynk said:
For compressibility of a gas... I am having a tough time finding anything. compressibility factor I can find, which is 1 for Hydrogen... but how does that relate to compressibility?
That is the compresibility, which for an ideal gas is exactly 1, and real gases have k ≈ 1.

fahraynk said:
Also... if a liquid is much more viscous than water... water is .001[Pa*sec] so say viscosity = 2... then would it likely be more or less compressible than water?
I will let more knowledgeable people answer, but I would be surprised if there was a link between compressibility and viscosity.
 
DrClaude said:
That is the compresibility, which for an ideal gas is exactly 1, and real gases have k ≈ 1.

Hi DrClaude,
From the value he give for liquid water, I don't think he was referring to the compressibility factor z. I think he was referring to the reciprocal of the bulk modulus. For an ideal gas, the compressibility is equal to 1/p. For liquid water, it looks like the value he gave has units of 1/kPa.

I will let more knowledgeable people answer, but I would be surprised if there was a link between compressibility and viscosity.
I agree with your assessment.
 
Chestermiller said:
Hi DrClaude,
From the value he give for liquid water, I don't think he was referring to the compressibility factor z. I think he was referring to the reciprocal of the bulk modulus. For an ideal gas, the compressibility is equal to 1/p. For liquid water, it looks like the value he gave has units of 1/kPa.
Thanks for the clarification.
 

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fahraynk said:
From Fundamentals of aerodynamics John D Anderson :
Compressibility Φ :
$$\phi = \frac{1}{\rho}\frac{d\rho}{dP}$$
$$dP=\rho\phi d\rho$$

He derives this by manipulating this equation : $$\phi=\frac{1}{v}\frac{dv}{dP}$$ where v is specific volume = 1/ρ

Also I got the compressibility of water from this source : http://hydrogen.physik.uni-wuppertal.de/hyperphysics/hyperphysics/hbase/tables/compress.html
If you apply this to an ideal gas, you get a compressibility of 1/P.
 
Chestermiller said:
If you apply this to an ideal gas, you get a compressibility of 1/P.
So, am I right to say that 1/(46.4e-6), water is 21551 times less compressible than an ideal gas? (at a pressure of 1atm)
 
fahraynk said:
So, am I right to say that 1/(46.4e-6), water is 21551 times less compressible than an ideal gas? (at a pressure of 1atm)
No. The comparison depends on the pressure. In the case of liquid water, the compressibility is very insensitive to pressure. In the case of an ideal gas, the compressibility is sensitive to the pressure. So you have to specify at which pressure you are making the comparison.
 
Chestermiller said:
No. The comparison depends on the pressure. In the case of liquid water, the compressibility is very insensitive to pressure. In the case of an ideal gas, the compressibility is sensitive to the pressure. So you have to specify at which pressure you are making the comparison.
1 atm.
The compressibility on this site if I am reading it correctly (I might not be) says 46.4e-6 at 1atm http://hydrogen.physik.uni-wuppertal.de/hyperphysics/hyperphysics/hbase/tables/compress.html
The compressibility of ideal gas, 1/P... is that pressure in atmospheres? Because then the compressibility at 1atm = 1, and 1/46.4e-6 = 21551
 
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fahraynk said:
1 atm.
The compressibility on this site if I am reading it correctly (I might not be) says 46.4e-6 at 1atm http://hydrogen.physik.uni-wuppertal.de/hyperphysics/hyperphysics/hbase/tables/compress.html
The compressibility of ideal gas, 1/P... is that pressure in atmospheres? Because then the compressibility at 1atm = 1, and 1/46.4e-6 = 21551
If the compressibility of the liquid water is 46.4E-4/atm (i.e., the pressure unit used for the pressure change is atm.), then I agree with this comparison.
 
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