Condition for formation of ionic bond

AI Thread Summary
The discussion centers on the conditions for the formation of ionic bonds, specifically questioning a textbook claim that a cation should be large while an anion should be small. Participants clarify that this condition is incorrect and emphasize that there is no requirement regarding the relative sizes of cations and anions for ionic bond formation. They highlight that ionic substances exist as crystal lattices rather than as single ionic bonds or molecules. The conversation concludes with the consensus that while ion sizes may influence the type of lattice structure formed, they do not dictate the formation of ionic bonds themselves.
gracy
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In my textbook one of the conditions for formation of ionic bond is given as
The cation should be large and anion should be small
But in the image of Nacl lattice structure ,we can see that it is other way around

I am not getting the reason,Is my textbook wrong ?
Or it has something to do with difference between ionic bond and lattice structure.I mean the picture I have attached is of crystal lattice not of single ionic bond between Sodium and chloride ion.

Thanks.
 
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gracy said:
But in the image of Nacl lattice structure ,we can see that it is other way around
upload_2015-4-19_12-56-42.jpeg
 
gracy said:
In my textbook one of the conditions for formation of ionic bond is given as
The cation should be large and anion should be small

Pure nonsense, no such condition.

Additionally, there is no such thing as a "single ionic bond" and a "single ionic molecule". All pure ionic substances exist only as ionic crystals (well, is some highly exotic conditions you can observe single molecules, it doesn't change the validity of the general statements).
 
Borek said:
Pure nonsense, no such condition.
That means my textbook is wrong.
 
Looks like.
 
And there is no such condition as
anion should be large and cation should be small either,right?
 
No, sizes don't matter at all.

They matter when it comes to the type of the lattice that they will build, but that's another story.
 

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