Cooling Tower's equation of humidity derivation

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SUMMARY

The derivation of the humidity equation, Hs = (Mw/Ma)(Ps/(P-Ps)), is based on the principles of ideal gas mixtures. In this equation, P represents the total pressure, and Ps denotes the saturation pressure of water vapor. The relationship is established by recognizing that the partial pressure of water vapor in saturated air is equal to the equilibrium vapor pressure at the mixture's temperature. Consequently, the mass of water vapor per unit mass of dry air is derived from the ratio of the saturation pressure to the difference between total pressure and saturation pressure, multiplied by the ratio of molecular weights.

PREREQUISITES
  • Understanding of ideal gas laws
  • Familiarity with concepts of partial pressure
  • Knowledge of molecular weight calculations
  • Basic principles of thermodynamics related to gas mixtures
NEXT STEPS
  • Study the derivation of the ideal gas law
  • Learn about the concept of partial pressures in gas mixtures
  • Explore the relationship between saturation pressure and temperature
  • Investigate the molecular weight of common gases, particularly water vapor and dry air
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Students and professionals in fields such as chemical engineering, environmental science, and HVAC engineering who are interested in understanding humidity calculations and thermodynamic principles related to gas mixtures.

Rathy Cato
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Humidity is known as mass of water vapor/mass of dry air

Hs (saturation) = (Mw/Ma){Ps/(P-Ps)}

P is total pressure
Ps is saturation pressure

what is the derivation for this equation?
 
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For an ideal gas mixture, the partial pressure of a substance is equal to the total pressure times the mole fraction of the substance. If the air is saturated with water vapor, then the partial of water vapor is equal to the equilibrium vapor pressure of water at the temperature of the mixture ps. Therefore, the number of moles of water vapor per mole of all other gasses in the air (i.e., per mole of dry air) is ps/(P - ps), where P is the total pressure. Multiplying by the ratio of the molecular weights give the mass of water vapor per unit mass of dry air.
 

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