Equilibrium Constant for Water Dissociation

In summary, the equilibrium constant (K) of a reaction with respect to the water equilibrium constant (KH2O) can be derived using conductivity measurements and the relationship between H+ and OH- ions in solution. This assumes that the concentration of water remains constant and does not affect the mathematical expression for K.
  • #1
vinayakp
4
0
How to derive equillibrium constant (K) of reaction with respect to water eq. constant (KH2O) ?

Reactions

H+ + HCO3- ----------> H2CO3


H+ + CO3-2 -----------> HCO3-

Fe2+ + Cl- ----------> FeCl+

Fe2+ + CH3COO- ----------> Fe( CH3COO)+
 
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  • #2
Please attempt to write the equations oneself. Is there not an example in one's Chemistry textbook?
 
  • #3
Here is just a wild guess about the dissociation constant for water; I do not know if it is actually how the constant was found:

Conductivity Measurements!

Pure, extra pure water could have been used, assuming dissociation would occur something like, in the simplest manner H2O <===> H+ + OH-
The resulting ions in solution will conduct electricity, therefore measurement of conductivity may correlate with concentration of the ions.

The concentration of the H2O is assumed not to change and does not occur in the mathematical expression. K = [H]*[OH]

Were you really asking about the thermodynamics of the process?
 
Last edited:

1) What is the equilibrium constant and why is it important?

The equilibrium constant, denoted by K, is a quantitative measure of the balance between the forward and reverse reactions in a chemical system at equilibrium. It is important because it allows us to predict the direction of a reaction and the relative amounts of reactants and products at equilibrium.

2) How is the equilibrium constant calculated?

The equilibrium constant is calculated by taking the ratio of the concentrations of products to the concentrations of reactants, each raised to the power of their respective coefficients in the balanced chemical equation. This calculation is done at a specific temperature and pressure, as these factors can affect the value of the equilibrium constant.

3) What is the relationship between the equilibrium constant and the direction of a reaction?

The equilibrium constant can be used to predict the direction of a reaction. If the value of K is greater than 1, the reaction will favor the products at equilibrium. If the value of K is less than 1, the reaction will favor the reactants at equilibrium. If the value of K is equal to 1, the reaction is at equilibrium and the amounts of reactants and products are equal.

4) How does temperature affect the equilibrium constant?

The equilibrium constant is dependent on temperature. As the temperature increases, the value of K may change, causing the reaction to favor the products or the reactants. This is due to the change in the energy of the molecules and their ability to overcome the activation energy barrier.

5) What are the units of the equilibrium constant?

The units of the equilibrium constant vary depending on the reaction and the concentrations used. However, the units will always be in terms of concentration, such as molarity (M) or partial pressure (atm). It is important to pay attention to the units when using the equilibrium constant in calculations.

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